Dispose() is called by the user of an object to indicate that he is finished with it, enabling that object to release any unmanaged resources it holds. Finalize() is called by the run-time to allow an object which has not had Dispose() called on it to do the same. However

Dispose() operates determinalistically, whereas there is no guarantee that Finalize() will be called immediately when an object goes out of scope - or indeed at all, if the program ends before that object is GCed - and as such Dispose() is generally preferred.